Reactivity of hypervalent silicon and tin compounds toward electrophilic sulfur
2000
Abstract Sulfuration of hypervalent complexes of silicon and tin was attempted with several electrophilic sulfur reagents for making carbonsulfur bonds under almost neutral conditions. We provided a qualitative scale of reactivity between various hypervalent salts. Simple and practical methodologies involving non-odorous elemental sulfur were developed. It avoided the use of H 2 S or standardized organolithium and Grignard solutions with sulfur, under highly basic conditions.
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