Defects control in the synthesis of low-dimensional zinc oxide

Abstract Zinc oxide (ZnO) has recently gained interest in the semiconductor field. Controlling defects can lead to band-gap engineering and this concept was explored for the synthesis of ZnO with various types of defects. In this study, we describe a method to synthesize quasi one-dimensional ZnO using gold nanoparticles as a template, using which we successfully controlled defect types like oxygen vacancies, oxygen interstitials, and zinc interstitials. Because the rate determination was the generation of Zn, it will be possible to synthesize ZnO with only zinc interstitials by independent supply of CO and O 2 .