A novel strategy to prepare N, S-codoped porous carbons derived from barley with high surface area for supercapacitors
2020
Abstract In this work, barley derived N, S-codoped porous carbons are synthesized through a simple, one-step chemical activation method using copper citrate as an activating agent. The copyrolysis of barley and copper citrate contributes to the formation of numerous micro-/mesopores and high surface area. Owing to redox reactions between copper citrate and carbon matrix during the activation process, the as-prepared porous carbon possesses a ultrahigh specific surface area of 2139.6 m2 g-1, hierarchical porous architecture with a large pore volume of 1.16 cm3 g-1, and high nitrogen, oxygen and sulfur contents. The resultant carbon material with high porosity and appropriate heteroatom doping exhibits a high specific capacitance of 401.6 F g-1 at 0.5 A g-1 in a 6.0 M KOH electrolyte and good rate capability with the capacitance remaining 165.6 F g-1 at 100 A g-1. Additionally, the assembled symmetric carbon-based supercapacitor delivers a high energy density of 30.9 Wh kg-1 and superior long-term cycling stability of 94.8% capacitance retention after 20000 cycles in 1.0 M Na2SO4 electrolyte. This work provides a facile strategy to design high-surface-area porous carbons with adjustable pore structure and rich heteroatom amount, which holds a promising future for constructing high energy carbon-based supercapacitors.
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