Recent progress in liquid electrolytes for lithium metal batteries
2019
Abstract Li metal batteries are revived as the next-generation batteries beyond Li-ion batteries. The Li metal anode can be paired with intercalation-type cathodes LiMO 2 and conversion-type cathodes such as sulfur and oxygen. Then, energy densities of Li/LiMO 2 and Li/S,O 2 batteries can reach 400 Whkg −1 and more than 500 Whkg −1 , respectively, which surpass that of the state-of-the-art LIB (280 Whkg −1 ). However, replacing the intercalation-type graphite anode with the Li metal anode suffers from low coulombic efficiency during repeated Li plating/stripping processes, which leads to short cycle lifetime and potential safety problems. The key solution is to construct a stable and uniform solid electrolyte interphase with high Li + transport and high elastic strength on the Li metal anode. This review summarizes recent progress in improving the solid electrolyte interphase by tailoring liquid electrolytes, a classical but the most convenient and cost-effective strategy.
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