Silver-assisted optimization of band gap gradient structure of Cu(In,Ga)Se2 solar cells via SCAPS
2021
Abstract Recently, silver (Ag) substitution for copper (Cu) into Cu(In,Ga)Se2 (CIGS) films has attracted widespread attention due to the lower synthesis temperature and the enlarge band gap. In this paper, SCAPS simulation is employed to investigate the influence of Ag doped CIGS absorber layer on the lattice defect and band gap gradient. First, the impact of the [Ga]/([In] + [Ga]) (GGI) and [Ag]/([Ag] + [Cu]) (AAC) on the defect concentrations is calculated systematically. It is demonstrate that the compression (GGI > 0.25) is more likely to cause the tetragonal distortion compared with the tension (GGI
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