Mechanistic insights into an unusual side chain mediated N-Cα bond cleavage under collision induced dissociation conditions in the disulfide containing peptide conopressin
2020
Conopressin, a nonapeptide disulfide CFIRNCPKG amide, present in cone snail venom undergoes a facile cleavage at the Cys(6)-Pro(7) peptide bond to yield a disulfide bridged b6 ion. Analysis of the ...
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