Excitonic transitions in spherical inhomogeneous QD, new monocolor nanosource

Abstract We study in this investigation the excitonic transitions in new spherical nanosystems also called inhomogeneous quantum dots IQD. They are promising in many technological applications: photovoltaic, LED, QD Laser and quantum computing. The excitonic binding energy significantly increases; which gives them greater stability at room temperature. The well-semiconductors in these nanostructures become luminescent under dual control core–well, in a wide spectral range from near UV to near and medium infrared IR. These optical properties enriched the field of IQD which generally have a high quantum efficiency and high photostability. The IQD presented are made out off ZnSe/HgS/ZnSe; CdS/GaSb/CdS; ZnS/HgS/ZnS and CdS/InSb/CdS modeled by a spherical well with infinite potential. Our theoretical investigation shows that the high degree of confinement in the well retains the 1 s e − 1 p e − 2 s e ( 1 s h − 1 p h − 2 s h ) order, guarantees excitonic transitions and isolates the ground state 1 s e − 1 s h ( E 2 s e , h − E 1 p e , h can be exceed 6 eV). The strong confinement provided by the infinite barrier, reduces the population relaxation and limit the coupling between the well and the electrostatic environment. These results qualify the nanostructure as a monocolor source and a system of two levels.