Dielectric performance of polymer-based composites containing core-shell Ag@TiO2 nanoparticle fillers

This paper reports composites prepared by embedding core-shell Ag@TiO2 fillers into polytetrafluoroethylene. Ag nanoparticles were homogeneously coated with TiO2, to give a shell thickness of approximately ∼8–10 nm. The composite containing Ag@TiO2 nanoparticles with rutile shells exhibited better dielectric properties than the composite containing Ag@TiO2 nanoparticles with anatase shells. The relative permittivity (er) of the composite containing 70 vol. % filler was approximately 240 at 100 Hz, which was more than 100 times higher than that of pure polytetrafluoroethylene (er = 2.1). An effective medium percolation theory model is used to account for the dielectric constant of the composite.