Nanosorbent of hydroxyapatite for atrazine: A new approach for combating agricultural runoffs

Abstract The attention of current work was on the fabrication of effective nanoadsorbent of hydroxyapatite (HAp) for the controlled release of atrazine (ATZ) formulation. The ATZ-HAp complex (ATZ@HAp) was able to inhibit the growth of Brassica sp. under in situ conditions. This developed methodology aspires to cease the agricultural runoffs of ATZ applied with the HAp adjuvant and ensure their effective functioning. The efficacy of the protocol was mainly accomplished by adsorbing ATZ over the surface of HAp NPs that restricted its premature runoff and promoted the prolonged herbicidal efficiency. The influence of fundamental parameters i.e., HAp dose, ATZ dose and initial pH on the adsorption process was investigated systematically. The suitability of ATZ@HAp complex for real world application was adjudged after proofing its toxicological behaviour and its role in Zea mays plantations. The complex was found to be non-toxic and nurturing due to its phosphate rich nature. Further investigations of ATZ@HAp complex and its effect on the non-target species will help in establishing an effective framework for their commercial use in agricultural practices.