Structure–Performance Relationships on Co-Based Fischer–Tropsch Synthesis Catalysts: The More Defect-Free, the Better

Understanding and utilizing structure–performance relationships in catalytic nanomaterials is the epitome of catalysis science. Knowledge at the atomic level can potentially allow rational design of more selective and energy-efficient catalytic materials. Fischer–Tropsch synthesis on cobalt is an example of a complicated system that operates in a narrow process regime, and the nature of the reaction product is governed by numerous parameters. On an industrial model catalyst, we have simplified the structure of the active, metallic nanoparticles into a predominantly hexagonal close-packed structure via the use of a Co2C precursor. By varying the final reduction temperature, we could mildly modify catalyst microstructural properties at the nanoparticle (NP) level. Catalytic materials, although with minimal structural differences, showed significantly different performance. Evidently there is a narrow window for complete utilization of the hexagonal close-packed Co crystallites that lies between removal of l...