New Paracyclophane Phosphine for Highly Enantioselective Ruthenium-Catalyzed Hydrogenation of Prochiral Ketones

Murthy N. Cheemala,Maud Gayral,John M. Brown,Kai Rossen,Paul Knochel

New Paracyclophane Phosphine for Highly Enantioselective Ruthenium-Catalyzed Hydrogenation of Prochiral Ketones

2007

Murthy N. Cheemala
Maud Gayral
John M. Brown
Kai Rossen
Paul Knochel

The synthesis of a new paracyclophane phosphine is described. This ligand was highly efficient in the ruthenium-catalyzed asymmetric hydrogenation of various aromatic and heteroaromatic ketones.

Keywords:

Enantioselective synthesis
Photochemistry
Paracyclophane phosphine
Ruthenium
Organic chemistry
Catalysis
Asymmetric hydrogenation
Chemistry
Ligand

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