Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3)

Chung-wing Leung,Wenxu Zheng,Dexian Wang,Siu Man Ng,Chi Hung Yeung,Zhong-Yuan Zhou,Zhenyang Lin,Chak Po Lau

Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3)

2007

Chung-wing Leung
Wenxu Zheng
Dexian Wang
Siu Man Ng
Chi Hung Yeung
Zhong-Yuan Zhou
Zhenyang Lin
Chak Po Lau

Deuteration of organic molecules using D2O as the deuterium source is affected with catalytic systems based on the ruthenium solvento hydride complex TpRu(PPh3)(CH3CN)H. The deuteration reactions c...

Keywords:

Boron
Catalysis
Inorganic chemistry
Chemistry
Medicinal chemistry
Stereochemistry

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