Microstructural evolution in a superelastic metastable beta-Ti alloy

Abstract The microstructural evolution of Ti-24Nb-4Zr-8Sn wt.% during low-temperature ageing is examined by atom-probe tomography (APT) and X-ray diffraction (XRD). This ageing is deleterious to the desirable mechanical properties, such as ultra-low elastic modulus and superelasticity. Initially, the cold-rolled alloy possesses a martensitic α ′′ -precipitate/ β -matrix microstructure. On ageing, Ti-rich/solute-lean precipitates grow in linear arrangements, which are likely associated with dislocations. Additionally, the composition and number density of Nb-rich domains (which are associated with superelasticity) are quantified for the first time. The domains are unstable, but decrease in number density during ageing, causing the deterioration in mechanical properties.