Molecular alloys as phase change materials (MAPCM) for energy storage and thermal protection at temperatures from 70 to 85 °C

Abstract Molecular alloys, that combine a relatively high heat of melting with a suitable melting temperature adapted to the application temperature, are excellent materials for thermal protection and for thermal energy storage. Of special interest is the fact that, by making alloys of molecular materials; the range of melting can be adjusted over a range of temperatures. The present paper reports on the design of MAPCMs to be used for energy storage and thermal protection at temperatures from 70 to 85 °C. The aim is to use these materials for thermal protection in the catering sector in order to avoid proliferation of micro organisms; the minimal temperature required is higher than 65 °C. The work illustrates how some fundamental studies are helpful in choosing the right composition that is able to work at the temperature required for an application. Several molecular alloys using the n -alkanes are elaborated and characterized. The preparation of mixed crystals, their crystallographic and thermodynamic properties and stability, phase change behaviour, and their use in practical applications are reported.