Nitrogen Surface Catalyzed Recombination Efficiency from Two-Photon Laser Induced Fluorescence Measurements

Measurements of temperature and species gradients in the thermal boundary layer adjacent to different surfaces exposed to nitrogen plasma are made to characterize surface-catalyzed recombination. Laser-induced nitrogen atom fluorescence signals are obtained with submillimeter spatial resolution to provide a direct indication of surface-catalyzed reactivity. Further analysis of the measured quantities balancing the diffusive reactant flux with the consumption of atoms by surface reaction yields direct quantitative values for surface-catalyzed reaction rates and catalytic efficiencies. Materials tested in the present work include metals and quartz, and the surface-catalyzed recombination efficiencies are (8.05±2.01)×10−3, (5.74±1.44)×10−3, (2.10±0.53)×10−3, and (1.03±0.26)×10−4 for polished copper, cooled virgin nickel, unpolished copper, and cooled quartz, respectively. Comparisons between these values and previously published results suggest that this technique provides a useful means to characterize the ...