Removal of superparamagnetic corrosion products and contaminants from drinking water using activated carbon

AbstractParticulate matter separated from tap water using columns of coarse and fine activated carbon was characterized by means of chemical analysis, magnetization measurements, X-ray diffraction (XRD) and scanning electron microscopy (SEM)––energy dispersive X-ray spectrometry (EDS). A large fraction of the solids accumulated on the activated carbon consisted of iron oxides, in particular magnetite nanoparticles, and of iron oxyhydroxides, specifically goethite and lepidocrocite. These species formed as a result of corrosion of iron or carbon steel pipes. The removal of various iron species was measured using a two-column system consisting of a column of coarse activated carbon followed by a column of fine activated carbon. The results indicated that coarse activated carbon was only effective in removing oxyhydroxide particles, while the fine activated carbon was also able to remove nanoparticles of anhydrous iron oxides such as magnetite and maghemite. In addition, it was observed that while a majority...