Survey of Ligand Field Parameters of Strong Field d5 Complexes Obtained from the g Matrix

Abstract Using a newly proposed approach involving an internally consistent set of equations, the ligand field parameters Δ / ξ , V / ξ and k are obtained from literature values of the g matrix for strong field d 5 systems of various conformations in which | Δ / ξ |≤10. Qualitative analysis of the observed results is done using the Angular Overlap Model, AOM.