Bifunctional Guanidine Hydroxide and Related Organocatalysts
2015
Catalysts designed to connect a guanidine moiety and active hydrogens such as hydroxyl, amide, and amine functionalities through a chiral spacer will be discussed regarding their utilities in asymmetric synthesis. The active hydrogens coordinate with acceptor molecules through hydrogen bonding, thus achieving both activation and positional control in the transition states.
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