Extension of Surface Organometallic Chemistry to Metal-Organic Frameworks: Development of a Well-Defined Single Site [(≡Zr-O-)W(═O)(CH2tBu)3] Olefin Metathesis Catalyst.

Zeynabou Thiam,Edy Abou-Hamad,Büsra Dereli,Lingmei Liu,Abdul-Hamid Emwas,Rafia Ahmad,Hao Jiang,Abdulrahman Adamu Isah,Papa Birame Ndiaye,Mostafa Taoufik,Yu Han,Luigi Cavallo,Jean-Marie Basset,Mohamed Eddaoudi

Extension of Surface Organometallic Chemistry to Metal-Organic Frameworks: Development of a Well-Defined Single Site [(≡Zr-O-)W(═O)(CH2tBu)3] Olefin Metathesis Catalyst.

2020

Zeynabou Thiam
Edy Abou-Hamad
Büsra Dereli
Lingmei Liu
Abdul-Hamid Emwas
Rafia Ahmad
Hao Jiang
Abdulrahman Adamu Isah
Papa Birame Ndiaye
Mostafa Taoufik
Yu Han
Luigi Cavallo
Jean-Marie Basset
Mohamed Eddaoudi

We report here the first step by step anchoring of a W(≡CtBu)(CH2tBu)3 complex on a highly crystalline and mesoporous MOF, namely Zr-NU-1000, using a Surface Organometallic Chemistry (SOMC) concept...

Keywords:

Metal-organic framework
olefin metathesis
Catalysis
Organometallic chemistry
Crystal
Polymer chemistry
Chemistry
single site
Mesoporous material

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