Fischer-Tropsch合成におけるRu/Mn/Al2O3触媒活性および安定性に及ぼすマンガン塩種の影響

The effects of manganese salts on Ru/Mn/Al2O3 catalysts prepared by the impregnation method for Fischer-Tropsch synthesis were investigated. The catalysts were named Ru/Mn(N)/Al2O3, Ru/Mn(A)/Al2O3, Ru/Mn(S)/Al2O3 and Ru/Mn(Cl)/Al2O3 according to the manganese nitrate, manganese acetate, manganese sulfate and manganese chloride salts. In the slurry phase Fischer-Tropsch reaction, Ru/Mn(N)/Al2O3 showed high and stable catalytic performance for CO conversion and space time yield under the reaction conditions, whereas other catalysts were deactivated. The order of catalytic performance was Ru/Mn(N)/Al2O3 >> Ru/Mn(A)/Al2O3 > Ru/Mn(Cl)/Al2O3 ≅ Ru/Mn(S)/Al2O3. The catalyst porosity, CO chemisorption, XRD, TEM, TPR and XPS were observed, which indicated that the similar size of Ru particle and pore diameter at 8 nm on Ru/Mn(N)/Al2O3 may increase the number of active Ru atoms on the catalyst surface due to the formation of manganese chloride, resulting in the high catalytic activity and stability for Fischer-Tropsch synthesis.