Mössbauer and TEM studies of the perovskite system (1-y)La2/3\(A\)1/3TiO3·yLaFeO3

The microscopic nature of the Mossbauer phase analysis has been found as being particularly valuable in testing assumptions suggested by TEM results regarding the microdomain structure and the population of different lattice sites by iron ions in the perovskite system (1-y)La2/3\(A\)1/3TiO3·yLaFeO3 with 0.04normal conditions, but moderate heating in vacuo causes a partial reduction of ferric ions to ferrous ions.