Platanus acerifolia’s buds: additional non-polar metabolites and structure revision of two previous dihydrochalcone-like metabolites
2013
Abstract In addition to the methylated and prenylated flavonoids previously reported from Platanus acerifolia , the multistep chromatographic processing of the n -hexane extract of the fresh unripe buds resulted in the isolation of 11 metabolites. Besides six common wax constituents, the n -hexane portion led to the isolation of four gem -dimethylpyrano flavanones. They corresponded to two pairs of angular and linear isomers derived only from pinocembrin (5,7-dihydroxyflavanone). Additionally, a novel β-decadione was split into the major keto-enol tautomer as shown by the detailed NMR and EIMS analyses. Moreover, the structures of grenoblone and 4-hydroxygrenoblone, two previously reported dihydrochalcone-like metabolites, were revised according to the EIMS spectra.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
9
References
2
Citations
NaN
KQI