N-Substituted Hydroxysuccinimides from (S)-Malic Acid as New Reagents for Asymmetric Diels-Alder Additions to Enoates.
1990
Abstract (S)-N-Methyl-2-hydroxysuccinimide, easily available from natural (S)-malic acid, supplements the previously introduced (R)-pantolactone as chiral auxiliary for asymmetric Diels-Alder reactions of enoates, but yields products of opposite configuration. Practical large-scale preparations of enantiomer pairs of synthetically important Diels-Alder adducts, including adducts from crotonates, are described.
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