Optimization of the pollutant removal in partially unsaturated constructed wetland by adding microfiber and solid carbon source based on oxygen and carbon regulation

Abstract The partially unsaturated constructed wetland was demonstrated to be able to enhance the oxygen supplement for the microbial nitrification. However, the fast gravity flow of wastewater on the smooth surface of substrate in unsaturated zone led to a short contact time between wastewater and biofilm on the surface of substrate for the microbial pollutant oxidation process. While, the strengthened oxygen supplement also consumed organic carbon, intensifying the shortage of electron donator for the denitrification process. To further enhance the efficiency of both nitrification and denitrification processes, two strategies were conducted as follows: (1) adding microfiber in unsaturated zone to extend the hydraulic retention time (HRT) and improve the oxygenating efficiency; (2) adding slow-release carbon source (Poly butylenes succinate, PBS) as electron donor in saturated zone for denitrification. Results showed that the ammonia oxidation efficiency reached up to 97.0% in the microfiber-enhanced constructed wetland. Additionally, adding microfiber provided more sites for microbes and increased the total number of microbes in unsaturated zone. The addition of PBS in the saturated zone obviously improved the denitrification efficiency with the total nitrogen (TN) removal rate raising from 20.6 ± 4.0% to 90.4 ± 2.7%, which excellently solved the problem of poor denitrification efficiency caused by low ratio of carbon to nitrogen (C/N). In conclusion, the association of microfiber and PBS in partially unsaturated constructed wetland finally accomplished the thorough nitrogen removal.