Elastocaloric effect and mechanical behavior for NiTi shape memory alloys

The NiTi shape memory alloy exhibited excellent superelastic property and elastocaloric effect. Large temperature changes of 30 K upon loading and -19 K upon unloading were obtained at room temperature, which were higher than those of the other NiTi-based materials and among the highest values reported in the elastocaloric materials. The asymmetry of the measured temperature changes between loading and unloading process was ascribed to the friction dissipation. The large temperature changes originated from the large entropy change during the stress-induced martensite transformation (MT) and the reverse MT. A large coefficient-of-performance of the material (COPmater) of 11.7 was obtained, which decreased with increasing the applied strain. These results are very attractive in the present solid-state cooling which is potential to replace the vapor compression refrigeration technologies.