Measurement of calcium stable isotope tracers using cool plasma ICP-MS
1999
A method for the measurement of calcium isotopes (42Ca,
43Ca, and 44Ca) using quadrupole inductively coupled
plasma mass spectrometry (ICP-MS) is described. Interferences from
polyatomic ions such as
12C16O2+ and
40ArH2+ at the calcium masses are greatly
minimized by operating the ICP-MS in the cool plasma mode. Relative standard
deviations (RSD) for the 42Ca∶43Ca and
44Ca∶43Ca ratios were found to be about
0.25%. Sample preparation involved using ammonium oxalate at a pH of 8 to
separate calcium from samples such as serum, urine, feces, and breast milk. The
isotope ratio measurements were used to determine fractional absorption of
calcium by a lactating woman after intravenous administration of 42Ca
and ingestion of 44Ca.
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