A thermodynamic model for predicting phosphate capacity of CaO-based slags during hot metal dephosphorisation pretreatment process

A thermodynamic model for predicting phosphate capacity of the CaO-based slags over a temperature range from 1750 to 1793 K (1477–1520°C) during dephosphorisation pretreatment of hot metal has been developed based on the ion and molecule coexistence theory (IMCT), i.e. the IMCT– model. The developed IMCT– model has been verified to be valid through comparing with the measured and the predicted ones by four reported models from the literature. Besides the total phosphate capacity , the respective phosphate capacity of nine dephosphorisation products as P2O5, 3FeO·P2O5, 4FeO·P2O5, 2CaO·P2O5, 3CaO·P2O5, 4CaO·P2O5, 2MgO·P2O5, 3MgO·P2O5 and 3MnO·P2O5 can also be accurately predicted by the developed IMCT– model. The formed 3CaO·P2O5 accounts for 99.20% of dephosphorisation products comparing with the generated 4CaO·P2O5 for 0.80%. The results also revealed that the effects of slag chemical composition including slag oxidisation ability, slag basicity and the comprehensive influence of iron oxides FetO and basi...