Enantioselective Multidimensional Gas Chromatography of Some Secondary Alcohols and Their Acetates from Banana
1991
Using enantioselective MDGC the enantiomeric distribution of alkan-(alken-)2-yl-acetates from bananas is achieved. After simple acetylation their corresponding alcohols 2-pentanol, 2-hexanol, 2-heptanol and (Z)-4-hepten-2-ol respectively are also exactly stereodifferentiated by the same method. All compounds investigated ― esters as well as alcohols ― exhibit a remarkable excess of the (S)-enantiomers
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