Modulating Supramolecular Binding of Carbon Dioxide in a Redox-Active Porous Metal-Organic Framework

Gaining molecular-level insight into host–guest binding interactions is fundamentally important, but experimentally challenging. Here, Schroder and co-workers study CO2–host hydrogen bonding interactions in a pair of isostructural redox-active VIII/VIV MOFs using neutron scattering and diffraction techniques.