Spin chemistry of organometallic compounds 2. Interaction of N-bromohexamethyldisilazane with allyltriorganolsilanes

Abstract Two instances have been considered demonstrating the influence of organoelement substituent on the reactivity of radicals generated from R 3 MCH 2 CHCH 2 (M=Si or Sn) in photoinduced interaction with (Me 3 Si) 2 NBr. CIDNP studies has allowed to identify two different reaction mechanisms for M=Si or M=Sn which end up in two different sets of reaction products.