Stereoselective synthesis of thioxylooligosaccharides from S-glycosyl isothiourea precursors
2001
Abstract A stereoselective synthesis of thioxylo-di-, -tri-, -tetra- and -penta-saccharides from S -glycosyl isothiourea precursors is described. The synthesis was performed starting from 2,3,4-tri- O -acetyl-β- d -xylopyranosyl isothiouronium bromide using a triethylamine promoted reaction with 1,2,3-tri- O -benzoyl-4- O -trifluoromethanesulphonyl-β- l -arabinopyranose. The resulting 4-thioxylobiose was then converted into the corresponding isothiouronium bromide and used for the synthesis of 4,4′-dithioxylotriose. Higher homologues of the series and their α-methyl glycosides were also prepared.
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