Synthesis of poly(m-phenylenediamine)-coated hexagonal Co9S8 for high-performance supercapacitors
2018
Poly(m-phenylenediamine)-coated hexagonal Co9S8 was firstly synthesized by the polymerization with self-prepared hexagonal Co(OH)2 used as cobalt source, and the calcination with sulfur powder providing sulfur source. By adjusting the concentration of m-phenylenediamine in the polymerization process, the coating was achieved with the different coated results, further affecting their supercapacitor behaviors by improving diffusion path for fast electron transfer. The resulting Co9S8/PmPD electrodes demonstrate excellent electrochemical performance with high specific capacitance of 950.1 F g−1 at a current density of 0.5 A g−1, good rate performance of 81.1% capacitance retention as the current density grows from 0.5 to 20 A g−1, and almost no capacitance loss after 1000 cycles. Moreover, as asymmetric positive electrode material, the Co9S8/PmPD-1 shows high specific capacitance of 115.3 F g−1 at 0.5 A g−1, outstanding rate performance of 78.2% capacitance retention even increased to 20 A g−1, superior cycle stability of 87.9% capacitance retention after 5000 cycles at 2 A g−1 and largest energy density of 36.0 W h kg−1 at power density of 374.67 W kg−1. This novel Co9S8/PmPD composite suggests a bright prospect for supercapacitor applications.
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