Engineering Biopolymer-based Ultrafast Permeable Aerogel Membrane Decorated with Task-specific Fe-Al Nanocomposites for Robust Water Purification
2020
The present work
demonstrates an innovative strategy for robust
water purification using an engineered aerogel membrane fabricated
from biopolymers and task-specific Fe–Al-based nanocomposites.
The as-prepared ethylenediaminetetraacetate dianhydride cross-linked
chitosan- and agarose (7:3 weight ratio)-based aerogel membrane decorated
with α-FeOOH- and γ-AlOOH-based nanocomposites was characterized
using various analytical tools, which suggested formation of a highly
stable network interconnected through covalent and electrostatic interactions.
The optimized bionanocomposite-based aerogel (BNC-AG-0.1) membrane
showed macroporous and partial unidirectional short-range channels
with an ultralow density of 0.021 g·m–2, a
high swelling ratio of 1974%, and a remarkable pure water flux of
19,228 L·m–2·h–1 (>6-fold
higher flux compared to the reported aerogel membranes). The aerogel
membranes were successfully utilized for purification of diverse pollutants
such as dyes, emerging pollutants (EPs), arsenate, and fluoride in
a continuous flow method under gravitational force. The BNC-AG-0.1
membrane exhibits high rejection (95–98.6%) for both cationic
and anionic dyes with a flux rate of 1150–1375 L·m–2·h–1 and a rejection of 89–92%
for EPs with a flux rate of 1098–1165 L·m–2·h–1. Moreover, the BNC-AG-0.1 membrane showed
a qmax of 102.45 mg·g–1 (at pH 6.5) for As(V) with >93% rejection at a flow rate of 1000
L·m–2·h–1. Furthermore,
the aerogel membrane showed an excellent removal efficiency (92%)
of arsenic up to the 10th cycle and hence demonstrated as a potential
adsorption-based membrane for arsenic-free potable water. On the other
hand, the BNC-AG-0.1 membrane showed a qmax of 81.56 mg·g–1 (at pH 6.5) for F– removal with >99% rejection at a flow rate of 250 L·m–2·h–1. When applied for real-water
purification,
approximately 4734 L of safe drinking water (the F– concentration is less than the WHO permissible limit) per square
meter of the aerogel membrane can be obtained with a flux rate of
250 L·m–2·h–1. Overall,
the prepared aerogel membrane showed robust removal of a variety of
contaminants with ultrafast water permeation and established excellent
recyclability.
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