Discontinuous Subatmospheric Pressure Interface Reduces the Gas Flow Effects on Miniature CAPI Mass Spectrometer

In the range of miniature mass spectrometers, the miniature ion trap mass spectrometer with continuous atmospheric pressure interface (CAPI) shows good performance potential and advantages due to its excellent sensitivity and analysis speed. However, in previous cases, placing the ion trap directly near the skimmer aperture means it will suffer high gas shock, which may affect performance. In this study, an improved miniature CAPI ion trap mass spectrometer was developed by gas flow optimisation. According to the experimental results, excessive gas flow affects stability and resolution. The impact of the gas flow can be effectively reduced by reducing the inner diameter of the skimmer and adding an additional lens element to move the ion trap away from the skimmer aperture. However, this method will affect the sensitivity of the instrument to some extent, so a discontinuous subatmospheric pressure interface (DSPI) was developed to reduce the gas flow effects and improve the comprehensive performance. When...