Tetra­kis(1,3,4,6,7,8-hexa­hydro-2H-pyrimido[1,2-a]pyrimidin-9-ido-κ2 N 1,N 9)niobium(V) hexa­fluorido­phosphate

The title complex, [Nb(C7H12N3)4]PF6, features chelating hpp anions (hpp is 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrim­idine) that define a distorted dodeca­hedral coordination geometry based on an N8 donor set. The Nb atom is situated on a site of symmetry \overline{4}, and the PF6− anion has crystallographic fourfold symmetry.