Improved Synthesis of Tertiary Propargyl Alcohols by the Favorskii Reaction of Alkyl Aryl (Hetaryl) Ketones with Acetylene.

E. Yu. Shmidt,Ivan A. Bidusenko,Nadezhda I. Protsuk,A. I. Mikhaleva,Boris A. Trofimov

Improved Synthesis of Tertiary Propargyl Alcohols by the Favorskii Reaction of Alkyl Aryl (Hetaryl) Ketones with Acetylene.

2013

E. Yu. Shmidt
Ivan A. Bidusenko
Nadezhda I. Protsuk
A. I. Mikhaleva
Boris A. Trofimov

Tertiary propargyl alcohols bearing aryl or heteroaryl substituents are readily accessible from the corresponding ketones and acetylene under atmospheric pressure using a superbasic system.

Keywords:

Alkyl
Atmospheric pressure
Favorskii reaction
Acetylene
Aryl
Propargyl
Chemistry
Organic chemistry

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