Regio- and Enantioselective Catalytic Monoepoxidation of Conjugated Dienes: Synthesis of Chiral Allylic cis-Epoxides.

Jawahar L. Jat,Saroj Ranjan De,Ganesh Kumar,Adeniyi Michael Adebesin,Shyam K. Gandham,John R. Falck

Regio- and Enantioselective Catalytic Monoepoxidation of Conjugated Dienes: Synthesis of Chiral Allylic cis-Epoxides.

2015

Jawahar L. Jat
Saroj Ranjan De
Ganesh Kumar
Adeniyi Michael Adebesin
Shyam K. Gandham
John R. Falck

A new catalyst Ti(IV)-salan system efficiently promotes the diastereo- and enantioselective monoepoxidation of conjugated dienes using H2O2 even in the presence of other olefins and adjacent stereocenters.

Keywords:

Allylic rearrangement
Conjugated system
Stereocenter
Enantioselective synthesis
Catalysis
Chirality (chemistry)
Organic chemistry
Chemistry

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