Transport properties of LaSrNi1 − xScxOy solid solutions

The formation of LaSrNiO4-and LaSrScO4-based solid solutions with the general stoichiometry LaSrNi1 − xScxO4 (0 < x < 1) has been studied in air at temperatures from 700 to 1300°C. According to x-ray diffraction results, the former solid solutions exist in the composition range 0 < x ≤ 0.2. Their lattice parameters have been determined, and their resistivity and thermoelectric power have been measured as functions of temperature. Oxygen release and absorption measurements at temperatures from 20 to 1000°C and oxygen partial pressures from 2 to 330 Pa suggest that the presence of scandium has a stabilizing effect on the oxygen sublattice of the solid solutions. The possible mechanisms of this effect are discussed.