Alkali Metal Mediated Zincation of N‐Heterocyclic Substrates Using the Lithium Zincate Complex, (THF)Li(TMP)Zn(tBu)2 and Applications in in situ Cross‐Coupling Reactions.

Victoria L. Blair,David C. Blakemore,Duncan Hay,Eva Hevia,David Pryde

Alkali Metal Mediated Zincation of N‐Heterocyclic Substrates Using the Lithium Zincate Complex, (THF)Li(TMP)Zn(tBu)2 and Applications in in situ Cross‐Coupling Reactions.

2011

Victoria L. Blair
David C. Blakemore
Duncan Hay
Eva Hevia
David Pryde

The direct regioselective zincation is studied and the resulting zinc organics are quenched with iodine or employed in Pd-catalyzed Negishi cross-coupling reactions.

Keywords:

Zincate
Negishi coupling
Coupling reaction
Regioselectivity
Alkali metal
Quenching
Zinc
Lithium
Chemistry
Inorganic chemistry

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