CuCl/CCl4-Promoted Convenient Synthesis of Sulfonyl Amidines from Tertiary Amines and Sulfonyl Azides.

Xiaoliang Xu,Zhichuang Ge,Dongping Cheng,Lei Ma,Chunshan Lu,Qunfeng Zhang,Nan Yao,Xiaonian Li

CuCl/CCl4-Promoted Convenient Synthesis of Sulfonyl Amidines from Tertiary Amines and Sulfonyl Azides.

2010

Xiaoliang Xu
Zhichuang Ge
Dongping Cheng
Lei Ma
Chunshan Lu
Qunfeng Zhang
Nan Yao
Xiaonian Li

Promoted by CuCl/CCl4, a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.

Keywords:

Sulfonyl
Chemistry
Organic chemistry

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