PHOTOCHEMICAL REACTION BETWEEN TERTIARY ALLYLIC AMINES AND CHROMIUM CARBENE COMPLEXES : SYNTHESIS OF LACTAMS VIA A ZWITTERION AZA COPE REARRANGEMENT

Christopher J. Deur,Michael W. Miller,Louis S. Hegedus

PHOTOCHEMICAL REACTION BETWEEN TERTIARY ALLYLIC AMINES AND CHROMIUM CARBENE COMPLEXES : SYNTHESIS OF LACTAMS VIA A ZWITTERION AZA COPE REARRANGEMENT

1996

Christopher J. Deur
Michael W. Miller
Louis S. Hegedus

Photolysis of chromium carbene complexes in the presence of tertiary allylic amines resulted in a zwitterionic aza Cope rearrangement to produce unsaturated lactams in fair yield.

Keywords:

Allylic rearrangement
Zwitterion
Aza-Cope rearrangement
Carbene
Photochemistry
Organic chemistry
Chemistry
Chromium

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