Diphenyldiazomethane as a six-electron .mu.4-ligand in metal cluster chemistry: structural characterization of Ru5(CO)12(.mu.4-.eta.2-C.tplbond.CR)(.mu.4-N2CPh2)(.mu.-PPh2) (R = Ph) and the product of CO insertion into the nitrogen-nitrogen bond in Ru5(CO)13(.mu.4-.eta.2-C2R)(.mu.4-NC(O)NCPh2)(.mu.-PPh2) (R = iso-Pr)

Donato. Nucciarone,Nicholas J. Taylor,Arthur J. Carty

Diphenyldiazomethane as a six-electron .mu.4-ligand in metal cluster chemistry: structural characterization of Ru5(CO)12(.mu.4-.eta.2-C.tplbond.CR)(.mu.4-N2CPh2)(.mu.-PPh2) (R = Ph) and the product of CO insertion into the nitrogen-nitrogen bond in Ru5(CO)13(.mu.4-.eta.2-C2R)(.mu.4-NC(O)NCPh2)(.mu.-PPh2) (R = iso-Pr)

1986

Donato. Nucciarone
Nicholas J. Taylor
Arthur J. Carty

Ru 5 −(CO) 12 (μ 4 -η 2 -C≡CPh)(μ 4 -N 2 CPh 2 )(μ-PPh 2 ) cristallise dans le systeme orthorhombique, groupe d'espace P2 1 2 1 2 1 et sa structure est affinee jusqu'a R=0,040. Ru 5 −(CO) 13 (μ 4 -η 2 -C≡C-i-Pr)(μ 4 -NC(O)NCPh 2 )(μ-PPh 2 ) cristallise dans le systeme triclinique, groupe d'espace P1 avec R=0,032

Keywords:

Nitrogen
Cluster chemistry
Inorganic chemistry
Photochemistry
Chemistry
Ligand
Hydrazone
Inorganic compound
Molecule
Metal
Crystallography
Crystal structure
Stereochemistry
X-ray crystallography

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