Boltzmann-Based Empirical Model to Calculate Volume Loss during Spirit Ageing

The Boltzmann equation is applied to fit data of volume loss for evaporation (in %) during spirit ageing in northern white oak (Quercus Alba) standard barrels of 205 L (+/− 10 L) using a temperature and humidity controlled cellar. The Boltzmann equation satisfactory fitted to the experimental data of the volume loss against temperature at constant humidity. Two parameters of the Boltzmann equation showed a linear dependency on the relative humidity of the air, while the other two parameters exhibited a constant value independently of the air humidity. The found empirical mathematical model can be used to calculate the volume loss for evaporation of spirits (40% v/v of ethanol) during ageing in terms of relative humidity (range: 40%–95%) and temperature (range: 10–30 °C) with significant accuracy.