Process analysis of hydrogen production from biomass gasification in fluidized bed reactor with different separation systems

Abstract Gasification is one of the most effective and studied methods for producing energy and fuels from biomass as different biomass feedstock can be handled, with the generation of syngas consisting of H 2 , CO, and CH 4 , which can be used for several applications. In this study, the gasification of hazelnut shells (biomass) within a circulating bubbling fluidized bed gasifier was analyzed for the first time through a quasi-equilibrium approach developed in the Aspen Plus environment and used to validate and improve an existing bubbling fluidized bed gasifier model. The gasification unit was integrated with a water-gas shift (WGS) reactor to increase the hydrogen content in the outlet stream and with a pressure swing adsorption (PSA) unit for hydrogen separation. The amount of dry H 2 obtained out of the gasifier was 31.3 mol%, and this value increased to 47.5 mol% after the WGS reaction. The simulation results were compared and validated against experimental data reported in the literature. The process model was then modified by replacing the PSA unit with a palladium membrane separation module. The final results of the present work allowed comparison of the effects of the two conditioning systems, PSA and palladium membrane, indicating a comparative increase in the hydrogen recovery ratio of 28.9% with the palladium membrane relative to the PSA configuration.