Copper‐Catalyzed Desymmetric Intramolecular Ullmann C—N Coupling: An Enantioselective Preparation of Indolines.

2013 
The first highly enantioselective protocol for preparation of indolines and tetrahydroquinolines via Cu-catalyzed asymmetric desymmetrization of 2-propanamines and 3-pentaneamines, respectively is presented.
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