Electron cyclotron resonance plasma source for metalorganic chemical vapor deposition of silicon oxide films

An electron cyclotron resonance (ECR) plasma source was employed for low‐temperature (50–300 °C) metalorganic plasma‐enhanced chemical vapor deposition of silicon oxide films. The plasma was excited in mixtures of oxygen and tetraethylorthosilicate vapor, and oxygen and tris(trimethylsiloxy)boron (TTMSB) vapor. The operation pressure range was 1–50 mTorr; oxygen and metalorganic vapor flow rates varied from 10 to 100 sccm. Microwave power (f=2.45 GHz, P=100–1500 W) was introduced into a 15‐cm‐diam ECR chamber via a microwave quartz introduction window. A static magnetic field in the plasma chamber was generated by two Helmholtz coils. It had intensity near the microwave window, Bvw=875–935 G in a narrow plasma mode, and Bvw=1000–1100 G in a uniform plasma mode. Silicon dioxide films were deposited onto a 10‐cm‐diam silicon wafer located at 16 cm from the source output. A line‐averaged plasma density Ne was measured with a microwave interferometer (35 MHz) at 11 cm from the source output. In the mixture o...