The Mechanism of Bending in Co-Crystals of Caffeine and 4-Chloro-3-Nitrobenzoic Acid
2021
In a recent study, Dey et al.1
propose a mechanism of elastic bending in co-crystals of caffeine,
4-chloro-3-nitrobenzoic acid and methanol (1) in which mechanical interlocking
is proposed to allow for the reversible flexibility observed. We have now determined the mechanism to atomic
resolution using micro-focused synchrotron radiation,2 which is
different to that previously reported. When subjected to strain the
inter-molecular distances change and hydrogen-bonded dimers rotate over two orthogonal
directions to allow the compression and expansion producing flexibility.
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