A stereocontrolled synthesis of trans-allylic amines

Wayne J. Thompson,Thomas J. Tucker,John E. Schwering,James L. Barnes

A stereocontrolled synthesis of trans-allylic amines

1990

Wayne J. Thompson
Thomas J. Tucker
John E. Schwering
James L. Barnes

Abstract The palladium catalyzed coupling of allylic acetates with carbon nucleophiles generates urethane protected trans-allylic amines with exceptionally high stereoselectivity.

Keywords:

Catalysis
Nucleophile
Allylic rearrangement
Stereoselectivity
Palladium
Organic chemistry
Aliphatic compound
Carbon
Inorganic chemistry
Chemistry

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