Stable composite of flower-like NiFe-layered double hydroxide nucleated on graphene oxide as an effective catalyst for oxygen reduction reaction
2019
Abstract Nowadays, it is an urgent need but challenging to develop an efficient and resource-rich electrocatalysts with electrocatalysts activity for the oxygen reduction reaction (ORR) electrocatalyst. Therefore, we rationally designed and synthesized a unique 3-dimensional (3D) structure of flower-like NiFe-layered double hydroxide (NiFe-LDH) growing on graphene oxide (GO) with large surface area, widely-exposed active sites and good electrical conductivity, of which the weight percentage of GO in NiFe-LDH/GO was about 27.37%. Consequently, compared with pure NiFe-LDH (0.71 V (vs RHE), 95 mV dec −1 ) in alkaline electrolyte, the NiFe-LDH/GO possesses a relatively high onset potential of 0.88 V (vs RHE) and a smaller Tafel slope of 82 mV dec −1 . Impressively, the prepared optimized NiFe-LDH/GO presents a highly stability than commercial Pt/C after stability testing due to strong interaction between graphene oxide and LDHs. In view of the above properties, these composite materials have better research prospects and open up a new opportunity for rational design.
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