Reactions of stabilized phosphoranes with enol lactones
1977
Enol lactones in which the double bond is conjugated with an ester group react with ethoxycarbonyl-methylenetriphenylphosphoraneunder mild conditions to yield the normal Wittig product, derivedfrom the lactone carbonyl group. When the double bond is conjugated with a ketone group reaction occurs at both carbonyl groups. Factors influencing reactivity are discussed.
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